Starting with the proper material selection is essential to getting the outcomes you want during extrusion and when 3D printing. You should choose your material based on its properties and its processability, not the possibilities you hope it’ll give you.
To help you along with your journey, we’ll take you through the different factors you should consider while giving you real-life examples, so you know how to go about the right material selection for your specific need. These factors include:
Not all materials have the same processability or require the same settings for filament extrusion. For example, high-temperature polymers such as PEEK, PEKK, and PEI require special processing, transition, and purging techniques. Therefore, it’s important to know and learn these techniques before you start experimenting to avoid clogging your filament maker.
Polymers such as PP and HDPE are challenging to solidify as round filaments due to high crystallinity. While they are very safe to process with out equipment, they take time to master from the start.
Crystallites that can affect the roundness of some polymers
What do you want to achieve with your project?
Before you decide on a material, define your needs carefully. Your material selection may become a variable in your project, so if several materials meet all your needs, it would be wise to choose the one that’s easier to process at the end of the day.
If you want to test PP with copper powder and if your goal is to experiment with the additive copper, you might want to start by adding the copper with PLA. Compared to PP, PLA is easier to extrude and print.
PEEK is the most popular option if you need a material with high mechanical strength and temperature resistance, but there are other materials to choose from, such as PEEK and PEI. If you decide on PEEK, keep in mind the many different grades of PEEK to choose from; some are easier to extrude than others.
Spool of extruded PEEK filament
When considering which polymer to choose for your application, it is essential to know the different grades available. The grade of a polymer corresponds to one specific reference of a polymer type by one manufacturer.
ABS is a family of hundreds of grades of the same plastic. Each grade is unique, and luckily, each is usually associated with a specific technical data sheet that can help you with filament manufacturing or 3D printing. To simplify things, we can divide them into categories of types of grades.
The main difference between the categories is the flowing behavior of the molten polymer, which we can quantify with a clear viscosity indicator: the Melt Flow Index (MFI) in g/10min.
The MFI test is quite simple. It’s done by measuring the mass of molten polymer that can be pushed through a hole under standardized conditions. The higher the MFI, the more fluid the plastic is, but the lower its viscosity.
The MFI values are only estimates and not exact settings. The scale gives a general indication of which grades are easier to transform into filaments, but it does not mean that only extrusion grades can be processed with filament makers. Quite the contrary, our material specialists have been able to process many injection-molding grades successfully.
There are usually no material-technical datasheets for manufactured items. In this case, the MFI is unknown.
Recycling plastics usually comes with a few more challenges than processing virgin plastics. These challenges include:
Although these extra steps can be time consuming, but don’t let that stop you from trying! We have successfully extruded recycled plastic several times and have learned that it works well when all parameters are controlled.
Composites are typically composed of a polymer core and reinforcing material, such as chopped or continuous fiber. Composite materials have higher strength and stiffness than non-reinforced polymers and are capable of replacing some metals, such as aluminum.
Presently, chopped carbon fiber is the most popular composite material used in 3D printing. Carbon fiber pieces are mixed with other 3D printing plastics, such as nylon, ABS, and PLA.
More companies are 3D Printing composites to maker parts (via 3DNatives)
In order to create a composite, the additive must be mixed with the base polymer. There are two ways to ensure that the additive is dispersed throughout the polymer.
When experimenting, it’s advisable to start with a small percentage of additives (usually 5%wt) and gradually increase the rate. The particle size of the additive is also crucial; sizes around 100 microns have been found to work very well.
By choosing the right material and the right quality, you can achieve your goal effortlessly. A safe process allows you to quickly assess the workability of a particular grade and choose a different grade if necessary.
These guidelines can seem quite daunting, and you may focus on the limitations and constraints of material selection. But, in reality, they show the many opportunities and discoveries you can make in material selection and processing.